I saw some black walnut oil at Wal-Mart on a shopping trip last spring and decided to get it to see how it tasted. The label hinted at flavor--some oils are very subtle, with olive oil being the most obvious exception. It was also fairly pricey.
I put them into this recipe, adapted from tasteofhome.com:
2 1/2 sticks of butter (1 1/4 c), softened but not melted [note this is slightly reduced]
2 2/3 cups sugar
4 eggs
1 tablespoon vanilla extract
2 cups white flour
1 cup cocoa powder
1/2 teaspoon salt
...and I normally add a cup of nuts. I substituted 3/4 cup black walnut oil and 1 stick of butter for the fat instead of all butter. And, since I'm an inveterate whole grain lover, I used 1 cup of whole wheat flour and 1 cup of white flour. I used dark chocolate cocoa powder and Whey Low as the sweetener. The result needs baking longer than the 30 minutes advertised on the site--especially since, I have recently learned, my oven runs about 10 degrees cool (I suppose I should just up the temperature I bake everything at, but I've grown accustomed to it).
The result (apologies for the bad picture below) was more cakey than fudgy, but there was a noticeable black walnut flavor. Overall, it worked well.
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